Lewis structure generator | Lewis dot structure calculator (2024)

Lewis structure calculator

The Lewis Structure Generator that we put in your hands here is an excellent tool to obtain structures of more than 400 molecules.

To use the Lewis Structure Calculator follow these steps:

  1. Enter the formula of the molecule in the field provided for it. For example, if we want to obtain the Lewis structure of the Sulfate ion, SO4– 2, we must first enter the charge by typing (-2) or by entering -2 in the charge field and pressing the «Add» button. Then we write the rest of the formula being as follows: (-2)SO4. A list of common molecules is also provided.
  2. Once the formula has been entered, you just have to press the “Generate” button and a window with the desired Lewis structure will automatically be displayed. To save the image of the structure on your computer, you just have to click on “Download”.

In addition to the Lewis structure calculator, here is a summary of the main theoretical concepts related to Lewis dot diagrams and some examples.

Lewis structure definition | What is a Lewis dot diagram?

The formation of a chemical bond (ionic and covalent) involves the transfer of electrons or the exchange of electrons. Lewis structures can be used to represent valence shell electrons in a chemical bond.

The Lewis structure, proposed by Gilbert Newton Lewis, who introduced it for the first time in 1916, is a graphic representation of the sharing of electrons that occurs in chemical bonds between atoms of the same or different species. These bonds can be single, double, or triple.

These type diagrams are a simplified representation of the valence shell electrons in a molecule. Lewis structures can be made for molecules that contain covalent bonds and for coordination compounds. The reason is that electrons are shared in a covalent bond. In an ionic bond, it is more like one atom donating an electron to the other atom.

How to draw Lewis structures

Given a chemical formula corresponding to a molecule or molecular ion, the steps to obtain its Lewis structure are as follows:

  1. First, it is important to get a correct count of all the valence electrons. One way to do such a count is to write Lewis symbols for all the atoms in the formula and count all the “dots.” For an (uncharged) molecule, that count is the correct number of valence electrons. For polyatomic ions, add the valence electrons of all atoms in the formula and subtract one electron for each positive charge on a cation and add one electron for each unit negative charge on an anion.
  2. The second step is to draw a skeletal structure. Which will help us decide how the atoms will bond. Choose a central atom (we will take as examples small molecules for which there is only one central atom, and the other atoms, the peripheral atoms, are all attached to the central atom). Hydrogen (H) and fluorine (F) each have a valence of 1, and generally these will not be central atoms (bonded to more than one atom). Given a formula, the central atom is typically the first atom (eg ClF 4 ), although this convention is not always followed (eg HNO 3 ). Another good way to choose is to choose the least electronegative atom. Inevitably, there will be cases where it is possible to draw more than one skeletal structure.
    Draw bonds as lines between atoms. Each bond counts as 2 e .
  3. Add electrons as lone nonbonding pairs around peripheral atoms so they have octets (eight electrons total). Note that this does not apply to hydrogen H, which can only accommodate a duo (2 e ).
  4. Add the remaining pairs of electrons to the central atom so your octet is complete (if it isn’t already). Never exceed an octet for an atom of period 2! For periods 3 and larger, the atoms are large enough to accommodate more than one octet in their valence bond shell. If no more electrons are available and the central one does not yet have a full octet, a lone pair on a peripheral atom can be pushed into a second (or third) bond with the central atom. Carbon and nitrogen are second-period elements that commonly form double and triple bonds as central atoms, and oxygen as the peripheral atom is often in a double bond with the central atom.
  5. If all atoms in the second period and above have at least one octet, and no atom in the second period exceeds an octet, and the total number of electrons in bonds and lone pairs equals the total number of available valence electrons, then we have produced a valid Lewis structure. The convention for ions is to enclose the structure in parentheses and indicate the net charge in the upper right corner.

Note that there are some cases where the best Lewis structure has an incomplete octet on a central atom. Since it is often possible to draw more than one valid Lewis structure for a molecule or molecular ion, we will need to assess which ones are more plausible or make better chemical sense. As noted above, formal charge is used as a guide in that zero or a minimum total number of formal charges is generally best, and the formal charge of an atom is considered relative to its electronegativity. Remember, a Lewis structure is not the molecule, but just a graphical representation intended to convey certain information about it. Such a representation informs the prediction of the likely physical or chemical properties of the actual molecule or of the bulk substance that is composed of those molecules. One of the most common uses we make of a valid Lewis structure (and for this we don’t need the best Lewis structure, just any valid one) is to predict molecular shape and polarity.

Lewis structure examples

PCl3 lewis structure

Lewis structure generator | Lewis dot structure calculator (1)

CH2Cl2 lewis structure

Lewis structure generator | Lewis dot structure calculator (2)

XeF2 lewis structure

Lewis structure generator | Lewis dot structure calculator (3)

All structures in the examples have been generated with the Lewis structure calculator.

Table of Contents

  • 1 Lewis structure calculator
  • 2 Lewis structure definition | What is a Lewis dot diagram?
  • 3 How to draw Lewis structures
  • 4 Lewis structure examples
    • 4.1 PCl3 lewis structure
    • 4.2 CH2Cl2 lewis structure
    • 4.3 XeF2 lewis structure

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Lewis structure generator | Lewis dot structure calculator (2024)

FAQs

How to calculate Lewis dot structure? ›

Step 1: Determine the total number of valence electrons. Step 2: Write the skeleton structure of the molecule. Step 3: Use two valence electrons to form each bond in the skeleton structure. Step 4: Try to satisfy the octets of the atoms by distributing the remaining valence electrons as nonbonding electrons.

What is the name of the Lewis structure? ›

Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.

How do you know how many dots to put on a Lewis dot structure? ›

A Lewis electron dot symbol (or electron dot diagram or a Lewis diagram or a Lewis structure) is a representation of the valence electrons of an atom that uses dots around the symbol of the element. The number of dots equals the number of valence electrons in the atom.

What is the Lewis dot structure of a chemical reaction? ›

A Lewis Structure is a very simplified representation of the valence shell electrons in a molecule. It is used to show how the electrons are arranged around individual atoms in a molecule. Electrons are shown as "dots" or for bonding electrons as a line between the two atoms.

What is Lewis structure structural formulas? ›

CHARACTERISTICS OF LEWIS FORMULAS: Lewis formulas are structures that show the connectivity, or bonding sequence of the atoms, indicating single, double, or triple bonds. They should also show any formal charges and unshared electrons that might be present in the molecule.

What are the rules for writing Lewis dot structure? ›

Follow these steps to create a lewis dot structure for a molecule:
  1. Use the Periodic Table to determine the total number of valence electrons in a molecule. ...
  2. Apply the "octet rule." Atoms are "happy" when they have 8 electrons in their outer shell. ...
  3. Choose which atom will be in the center. ...
  4. Determine covalent bonds.
May 28, 2021

What is the correct Lewis dot structure for? ›

Lewis structures, also known as Lewis-dot diagrams, show the bonding relationship between atoms of a molecule and the lone pairs of electrons in the molecule. Lewis structures can also be useful in predicting molecular geometry in conjuntion with hybrid orbitals.

How many dots would be on a Lewis dot structure of CO2? ›

Lewis Structure of CO2

Carbon has four valence electrons, which make a total of four bonds. So there are four dots around carbon. Oxygen only needs two bonds, which are shown by the single dots to the left and right of the O.

What is an example of a Lewis structure? ›

Lewis Structures

For example, when two chlorine atoms form a chlorine molecule, they share one pair of electrons: The Lewis structure indicates that each Cl atom has three pairs of electrons that are not used in bonding (called lone pairs) and one shared pair of electrons (written between the atoms).

What does the Lewis dot structure tell us? ›

Lewis structures (also known as Lewis dot structures or electron dot structures) are diagrams that represent the valence electrons of atoms within a molecule. These Lewis symbols and Lewis structures help visualize the valence electrons of atoms and molecules, whether they exist as lone pairs or within bonds.

What is the dot notation of the Lewis structure? ›

Each Lewis dot symbol consists of the chemical symbol for an element surrounded by dots that represent its valence electrons, the total number of s and p electrons in the outermost shell available for bonding.

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